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Chain
Termination
zirconocene/MAO catalysts are about 10 to 100 times more active for ethene
polymerisation than conventional Ziegler catalyst systems. Every Zr atom
forms about 46 000 polymer chains per hour. Calculations show that one
ethene unit is inserted every 3 x 10-5 seconds, a very rapid
rate of reaction indeed.
Chain termination occurs when a Zr-H bond forms before the addtion of
another ethene molecule.
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